Table 3.
Volatile compounds (mg/L)1) in fermented liquors (n=2).

Code KI2) Volatile compound3) Sample4) Id5)
SS SJ HK JE
Ester
es1 <800 ethyl acetate 2.14 0.03 0.62 1.05 A
es2 1076 ethyl butyrate 0.23 0.08 0.25 1.94 A
es3 1179 ethyl pentanoate 0.09 0.25 0.03 1.78 B
es4 1253 Isoamyl formate 40.78 - - - B
es5 1282 ethyl hexanoat 0.34 5.64 3.85 45.34 A
es6 1373 ethyl heptanoate 0.24 0.6 - 4.5 A
es7 1464 ethyl octanoate 14.94 16.7 31.59 380.59 B
es8 1482 Isopentyl hexanoate 0.17 0.24 0.17 3.72 B
es9 1561 ethyl nonanoate 0.42 1.28 0.23 37.8 A
es10 1569 butyl octanoate 0.09 - 0.26 4.53 A
es11 1569 ethyl 2-octenoate - 0.3 - 1.02 A
es12 1594 ethyl 4-decenoate 0.22 0.55 - - B
es13 1644 ethyl decanoate 13.9 19.97 30.24 303.42 A
es14 1660 3-methylbutyl octanoate 0.29 0.53 0.79 11.63 B
es15 1678 diethyl butanedioate 0.12 0.33 0.31 6.58 B
es16 1727 ethyl benzeneacetate 0.72 0.79 - - B
es17 1743 Isobutyl decanoate 0.15 0.07 0.14 0.92 A
es18 1772 methyl 2-hydroxy-benzoate 0.35 0.27 0.29 4.08 B
es19 1786 ethyl 4-hydroxybutanoate 0.95 0.62 0.51 20.09 B
es20 1800 2-phenylethyl acetate 26.92 0.59 8.54 46.41 A
es21 1821 ethyl dodecanoate 3.29 3.99 7.64 87.48 A
es22 1835 Isoamyl decanoate 0.21 0.13 0.29 2.16 A
es23 1987 ethyl tetradecanoate 2.29 1.77 8.64 90.09 A
es24 2213 ethyl hexadecanoate 8.4 3.93 19.26 206.79 A
es25 2254 ethyl 9-hexadecenoate - - 1.18 2.88 A
es26 >2300 ethyl 9-octadecenoate 1.11 0.06 0.35 8.9 B
es27 >2300 ethyl linoleate 0.97 0.23 1.09 14.12 B
Total ester 119.33 70.16 116.27 1287.82
Alcohol
al1 1024 1-propanol 0.16 0.04 0.90 7.37 A
al3 1097 2-methyl-1-propanol 1.63 0.20 1.98 45.46 A
al4 1194 1-butanol 4.27 0.07 0.35 9.36 A
al2 1215 Isoamyl alcohol (3-methyl-1-butanol) 5.13 2.17 41.80 23.55 A
al5 1274 1-pentanol 22.02 40.20 - 559.13 A
al6 1388 1-hexanol 0.28 0.69 - - A
al7 1411 3-ethoxy-1-propanol 0.14 0.13 0.73 6.00 A
al8 1585 2,3-butanediol 0.11 - 2.80 10.25 A
al9 1710 3-(methylthio)-1-propanol 0.42 0.16 0.27 - B
al10 1881 2-phenyl ethanol 92.33 44.80 57.93 685.71 A
Total alcohol 126.49 88.46 106.76 1346.83
Acid
ac1 1478 acetic acid 0.21 - 5.42 13.52 A
ac2 2000 octanoic acid 0.24 0.23 0.40 0.45 A
ac3 2100 nonanoic acid 0.29 0.13 0.05 - A
Total acid 0.74 0.35 5.87 13.97
miscellaneous
mc1 <800 acetal - 1.77 - 54.37 B
mc2 1083 2-fluoropropene 0.03 0.06 1.19 34.51 B
mc3 1141 1-(1-ethoxyethoxy)-pentane 0.03 - 0.04 1.60 A
mc4 1388 methyl cyclopentane 0.19 - 0.08 - B
mc5 1455 1,3-bis(1,1-dimethylethyl)-benzene 0.14 0.12 0.10 3.39 B
mc6 1477 1,2-dimethyl-hydrazine 0.09 0.09 0.08 - B
mc7 1968 dihydro-5-pentyl-2(3H)-furanone 1.25 - - 9.83 B
mc8 1983 4-pentylbutan-4-olide 0.11 0.19 - - B
mc9 2101 2-methoxy-4-vinylphenol 3.36 1.13 0.09 4.72 A
Total miscellaneous 5.20 3.36 1.58 108.42
Average of the mg/L (n=2)eq
Kovats indices of unknown compounds on DA-WAX column
Compounds by order of their Kovats indices in a chemical class
See code name in Table 1.
Volatiles were identified based on the following criteria: A, mass spectrum and retention index consistent with those of an authentic standard: B, mass spectrum consistent with that of the Wiley 275 mass spectrum database.